Technologies

Knowing how to tame the tiger

What is fluorination?

Fluorination is defined as the surface treatment of plastics and other materials with fluorine gas. Fluorination makes preliminary, intermediate and end products suitable for further processing or later use. By applying fluorine-nitrogen or fluorine-air compounds to the base material, a micrometer-thick layer of the surface is turned into a “functional thin film”. This film alone determines how the carrier material interacts with the environment.

Barrier fluorination:

Barrier fluorination uses compounds with a fluorine content of 1% - 20%. The aim of this surface treatment is to modify the base material to protect the surface from all types of solvents, such as chemicals, organic solvents, oils and fuels. Fluorination can also protect plastic surfaces against penetration by moisture, vapours, odours and aromas. Fluorinated surfaces even offer protection against attack by bacteria and microorganisms.

Surface activation:

Fluorine-air compounds with a low fluorine content improve the adhesion properties of plastics and other base materials. In contrast to barrier fluorination, this treatment increases the surface energy and gives the surface hydrophilic properties. Typical applications for this technology include the painting and structuring of plastics, the bonding of plastics to one another or to other materials, the natural and artificial fibres industry, the manufacture of membranes and filter materials and the production of fibre-reinforced construction materials.

   
 

Processes

INLINE & OFFLINE systems:

Depending on the type of use, we distinguish between continuous or semi-continuous “INLINE” systems and discontinuous “OFFLINE” systems.

With the INLINE method, fluorination takes place during the manufacturing process - during the blow-moulding of packaging containers, for example.

Where the OFFLINE method is used, manufacturing and fluorination are separate processes. The parts to be fluorinated are treated separately in vacuum chamber reactors, independently of the manufacturing process.

Both methods can be used on a large scale and for many years they have been a key part of Air Products' offerings.


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